Hydrated electron Trihydroxyaluminum(III)

Peiris, S.A.; Freeman, G.R.
Can. J. Chem. 69, 157-166 (1991)

Reaction: e_aq^- + Al(OH)₃ ®
Solvent: H₂O

Activation energy = 34(kJ mol^-1), Log(A) = 16.359, Temperature range 283 to 363 K
k = 2.5 × 10¹⁰(L mol^-1 s^-1), T = 298K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in soln. contg. (2-34) × 10^-6 mol L^-1 Al(ClO₄)₃.

Peiris, S.A.; Freeman, G.R.
Can. J. Chem. 69, 884-892 (1991)

Reaction: e_aq^- + Al(OH)₃ ®
Solvent: H₂O

Activation energy = 34(kJ mol^-1), Log(A) = 16.359, Temperature range 283 to 363 K
k = 2.5 × 10¹⁰(L mol^-1 s^-1), T = 298K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in soln. contg. (2-24) × 10^-6 mol L^-1 Al(ClO₄)₃.

Anbar, M.; Hart, E.J.
J. Phys. Chem. 69, 973-977 (1965)

Reaction: e_aq^- + Al(OH)₃ ®
Solvent: H₂O

k = 2.0 × 10⁹(L mol^-1 s^-1), pH = 6.8

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

D.k., counterion ClO₄^-; pK_h = 4.9, 5.43, 5.86, 11.22.