Hydrogen atom Thiocyanic acid

Elliot, A.J.; Geertsen, S.; Buxton, G.V.
J. Chem. Soc., Faraday Trans. 1 84, 1101-1112 (1988)

Reaction: H· + HSCN ® (HSCN)H·
Solvent: H₂O

k = 3.6 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Derived from fitting to complex mechanism

Competition kinetics; obs. G[(SCN)₂·^-] in neutral and 3.6 mol L^-1 HClO₄ soln. satd with oxygen.