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Decay constant for singlet oxygen in the solvent: Dimethyl sulfoxide | ![]() |
Decay rate is ~5.2 x 104 s–1
Experimental method: continuous photolysis, substrate consumption
Sensitizer is RB,
Substrate is DPBF, A' = 2M2P. Measured betaA' = 0.055 mol L–1,
assumed kA' in MeOH and DMSO are the same, used betaA' = 0.15 and kd
= 1.4 x 105 s–1 in MeOH.
Lifetime is ~3.0 x 10–5 s
Decay rate is ~3.3 x 104 s–1
Method not reported, may be direct method given in ref. [719325].