SOX_1_64

Decay constant for singlet oxygen in the solvent:

Ethanol

Naether, D.U.; Gilchrist, J.R.; Gensch, T.; Roeder, B.
Photochem. Photobiol. 57(6): 1056-9 (1993)

Lifetime is 1.3 x 10^–5 s
Decay rate is 7.9 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is BPhe a.

Wang, W.; Tang, Y.; Yu, Y.
Yingyong Huaxue 6(3): 54-6 (1989)

Lifetime is 1.4 x 10^–5 s
Decay rate is 7.1 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is HP.

Wang, W.; Tang, Y.; Yu, Y.
Yingyong Huaxue 6(3): 54-6 (1989)

Lifetime is 1.6 x 10^–5 s
Decay rate is 6.3 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is RB.

Wang, W.; Tang, Y.; Yu, Y.
Yingyong Huaxue 6(3): 54-6 (1989)

Lifetime is 1.3 x 10^–5 s
Decay rate is 7.7 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is MB.

Valduga, G.; Nonell, S.; Reddi, E.; Jori, G.; Braslavsky, S.E.
Photochem. Photobiol. 48(1): 1-5 (1988)

Lifetime is 1.4 x 10^–5 s
Decay rate is 7.1 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is Zn(pc)(py)₂.

Krasnovsky, A.A.,Jr.; Egorov, S.Yu.; Nasarova, O.V.; Yartsev, E.I.; Ponomarev, G.V.
Stud. Biophys. 124(2-3): 123-42 (1988)

Lifetime is 1.5 x 10^–5 s
Decay rate is 6.7 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is H₂TPPS^4–.

Redmond, R.W.; Heihoff, K.; Braslavsky, S.E.; Truscott, T.G.
Photochem. Photobiol. 45(2): 209-13 (1987)

Lifetime is 1.4 x 10^–5 s
Decay rate is 7.4 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, thermal buildup
Sensitizer is HP.

Darmanyan, A.P.
Khim. Fiz. 6(9): 1192-8 (1987)

Lifetime is 1.4 x 10^–5 s
Decay rate is 7.2 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is An.

Jardon, P.; Lazortchak, N.; Gautron, R.
J. Chim. Phys. Phys.-Chim. Biol. 84(10): 1141-5 (1987)

Decay rate is 8.3 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, substrate disappearance, product buildup
Sensitizer is An;
Substrate is MDH.

Rossbroich, G.; Garcia, N.A.; Braslavsky, S.E.
J. Photochem. 31(1): 37-48 (1985)

Lifetime is 1.2 x 10^–5 s
Decay rate is 8.3 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, thermal buildup
Sensitizer is An.

Gorman, A.A.; Hamblett, I.; Smith, K.; Standen, M.C.
Tetrahedron Lett. 25(5): 581-4 (1984)

Lifetime is 1.3 x 10^–5 s
Decay rate is 7.7 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is 2-ACN.

Fuke, K.; Ueda, M.; Itoh, M.
J. Am. Chem. Soc. 105(5): 1091-6 (1983)

Lifetime is 1.1 x 10^–5 s
Decay rate is 9.1 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, thermal buildup
Sensitizer is Ery.

Rodgers, M.A.J.
J. Am. Chem. Soc. 105(20): 6201-5 (1983)

Lifetime is 1.5 x 10^–5 s
Decay rate is 6.5 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is HPDME.

Salokhiddinov, K.I.; Byteva, I.M.; Gurinovich, G.P.
J. Appl. Spectrosc. 34(5): 561-4 (1981)

Lifetime is 9.6 x 10^–6 s
Decay rate is 1.0 x 10⁵ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is PdMPDME.

Parker, J.G.; Stanbro, W.D.
Johns Hopkins APL Tech. Dig. 2(3): 196-9 (1981)

Lifetime is ~1.1 x 10^–5 s
Decay rate is ~9.1 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is HP.

Wilkinson, F.
Singlet Oxygen, Reactions with Organic Compounds and Polymers, B. Ranby and J.F. Rabek (eds.), John Wiley & Sons, New York, N.Y., 1976, p.27-35

Lifetime is 1.0 x 10^–5 s
Decay rate is 1.0 x 10⁵ s^–1

Experimental method: pulsed laser photolysis, substrate disappearance
Sensitizer is MB,
Substrate is DPBF.

Young, R.H.; Brewer, D.R.
Singlet Oxygen, Reactions with Organic Compounds and Polymers, B. Ranby and J.F. Rabek (eds.), John Wiley & Sons, New York, N.Y., 1976, p.36-47

Lifetime is 1.9 x 10^–5 s
Decay rate is 5.3 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, substrate disappearance
Sensitizer is MB,
Substrate is DPBF.

Merkel, P.B.; Kearns, D.R.
J. Am. Chem. Soc. 94(21): 7244-53 (1972)

Lifetime is 1 x 10^–5 s
Decay rate is 8 x 10⁴ s^–1

Experimental method: pulsed laser photolysis, substrate disappearance
Sensitizer is MB,
Substrate is DPBF.

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