Diazodi(4-chlorophenyl)methane Singlet oxygen

Bethell, D.; McKeivor, R.
J. Chem. Soc., Perkin Trans. 2, 327-333 (1977)

Reaction: Diazodi(4-chlorophenyl)methane + ¹O₂^* ® products
Reference Reaction: 9,10-Dimethylanthracene + ¹O₂^* ®
Solvent: CH₃CN

k_react = 7.3 × 10⁸(L mol^-1 s^-1), k_reference = 1.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Bethell, D.; McKeivor, R.
J. Chem. Soc., Perkin Trans. 2, 327-333 (1977)

Reaction: Diazodi(4-chlorophenyl)methane + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 6.6 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue. used solvent k_d = 3.3 × 10⁴ s^-1.

Bethell, D.; McKeivor, R.
J. Chem. Soc., Perkin Trans. 2, 327-333 (1977)

Reaction: Diazodi(4-chlorophenyl)methane + ¹O₂^* ® products
Reference Reaction: Diazodiphenylmethane + ¹O₂^* ®
Solvent: CH₃CN

k_react = 7.5 × 10⁸(L mol^-1 s^-1), k_reference = 1.4 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Bethell, D.; McKeivor, R.
J. Chem. Soc., Perkin Trans. 2, 327-333 (1977)

Reaction: Diazodi(4-chlorophenyl)methane + ¹O₂^* ® products
Reference Reaction: Diazodiphenylmethane + ¹O₂^* ®
Solvent: MeOH

k_react = 3.8 × 10⁸(L mol^-1 s^-1), k_reference = 6.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.