Leucomalachite Green Singlet oxygen

Stevens, B.; Kaplan, S.J.
Mol. Photochem. 9, 205-211 (1979)

Reaction: Leucomalachite Green + ¹O₂^* ® products
Reference Reaction: 9-Phenylanthracene + ¹O₂^* ®
Solvent: C₆H₅CH₃

k_react = < 1 × 10⁵(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm

Photosensitizer = 9-Phenylanthracene.

Stevens, B.; Kaplan, S.J.
Mol. Photochem. 9, 205-211 (1979)

Reaction: Leucomalachite Green + ¹O₂^* ® products and/or physical quenching
Reference Reaction: 9,10-Dimethylanthracene + ¹O₂^* ®
Solvent: C₆H₅CH₃

k/k_reference = 5
k = 2 × 10⁸(L mol^-1 s^-1), b_ref = 1.5 × 10^-3(mol L^-1), k_reference = 3.5 × 10⁷(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm

Photosensitizer = 9,10-Dimethylanthracene.