Bis(dithioacetylacetonato)nickel(II) Singlet oxygen

Guillory, J.P.; Cook, C.F.
J. Polym. Sci., Polym. Chem. Ed. 11, 1927-1937 (1973)

Reaction: Nickel(II) bis[dithioacetylacetonate] + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₆H₅Br

k = 2.3 × 10⁸(L mol^-1 s^-1), T = 273K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 4.0 × 10⁷ L/(mol·s); used solvent k_d = 13 × 10⁴ s^-1.