Methyl 4-methylphenyl sulfide Singlet oxygen

Inoue, K.; Matsuura, T.; Saito, I.
Tetrahedron 41, 2177-2181 (1985)

Reaction: Methyl 4-methylphenyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: Benzene

k = 1.5 × 10⁶(L mol^-1 s^-1), T = 308K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 5.4 × 10⁴ s^-1; ¹O₂* from MNPO₂.

Inoue, K.; Matsuura, T.; Saito, I.
Tetrahedron 41, 2177-2181 (1985)

Reaction: Methyl 4-methylphenyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH, 50%, H₂O, 50%

k = 3.2 × 10⁷(L mol^-1 s^-1), T = 308K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 2.8 × 10⁵ s^-1; ¹O₂* from MNPO₂.

Monroe, B.M.
Photochem. Photobiol. 29, 761-764 (1979)

Reaction: Methyl 4-methylphenyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 4.6 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Kacher, M.L.; Foote, C.S.
Photochem. Photobiol. 29, 765-769 (1979)

Reaction: Methyl 4-methylphenyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 3.1 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = 2,5-Diphenylfuran; used solvent k_d = 1.1 × 10⁵ s^-1.