2-Methyl-2-nitrosopropane Singlet oxygen

Singh, P.; Ullman, E.F.
J. Am. Chem. Soc. 98, 3018-3019 (1976)

Reaction: (CH₃)₃C(NO) + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: CH₂Cl₂, 94%, MeOH, 6%

k = 9.3 × 10⁹(L mol^-1 s^-1)

Experimental method: Chemical reaction
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene, k for indicator = 4.0 × 10⁷ L/(mol·s); used solvent k_d = 1.1 × 10⁴ s^-1; ¹O₂* from (PhO)₃PO₃.