5,5-Dimethyl-1,3-cyclohexanedione Singlet oxygen

Kruk, I.; Lichszteld, K.; Michalska, T.; Bounias, M.
Z. Naturforsch., C, Biosci. 44C, 39-44 (1989)

Reaction: Dimedone + ¹O₂^* ® products and/or physical quenching
Reference Reaction: DPBF + ¹O₂^* ®
Solvent: D₂O

k = 9 × 10⁷(L mol^-1 s^-1), pH = 11.2, T = 310K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran¹O₂*; from Dopamine/H₂O₂; used solvent k_d = 1.5 × 10⁴ s^-1.

Kruk, I.; Lichszteld, K.; Michalska, T.; Bounias, M.
Z. Naturforsch., C, Biosci. 44C, 39-44 (1989)

Reaction: Dimedone + ¹O₂^* ® products and/or physical quenching
Reference Reaction: DPBF + ¹O₂^* ®
Solvent: D₂O

k = 1.2 × 10⁸(L mol^-1 s^-1), pH = 11.2, T = 310K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran¹O₂*; from DOPA/H₂O₂; used solvent k_d = 1.5 × 10⁴ s^-1.