2,3-Dimethylenebicyclo[2.2.2]octane Singlet oxygen

Clennan, E.L.; Matusuno, K.
J. Org. Chem. 52, 3483-3485 (1987)

Reaction: 2,3-Dimethylenebicyclo[2.2.2]octane + ¹O₂^* ® products and/or physical quenching
Solvent: CD₃COCD₃

k = 1.7 × 10⁶(L mol^-1 s^-1), T = 195K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = 1,3-Diphenylisobenzofuran; k_d not given. [O₂] = O₂.