9-Methylanthracene Singlet oxygen

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Benzene

k = 2.3 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Rubrene. used solvent k_d = 4.2 × 10⁴ s^-1.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Ethanol

k = 2.0 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB. used solvent k_d = 8.3 × 10⁴ s^-1.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Ethanol, 50%, Water, 50%

k = 1.7 × 10⁷(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB. used solvent k_d = 2 × 10⁵ s^-1.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Water

k = 3.8 × 10⁷(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB; 0.068 mol L^-1 PEO; k_d not given.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Water

k = 9.6 × 10⁷(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB. used solvent k_d = 3 × 10⁵ s^-1.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 1.7 × 10⁷(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB; used solvent k_d = 2.4 × 10⁵ s^-1; 0.1 mol L^-1 SDS.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 1.4 × 10⁷(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB; used solvent k_d = 2.5 × 10⁵ s^-1; 0.015 mol L^-1 CTAB.

Rubio, M.A.; Araya, L.; Abuin, E.B.; Lissi, E.A.
An. Asoc. Quim. Argent. 73, 301-309 (1985)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol

k = 2.0 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = MB. used solvent k_d = 1 × 10⁵ s^-1.

Monroe, B.M.
J. Phys. Chem. 82, 15-18 (1978)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 8.1 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Stevens, B.; Perez, S.R.; Ors, J.A.
J. Am. Chem. Soc. 96, 6846-6850 (1974)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₆H₆

k = 3.2 × 10⁶(L mol^-1 s^-1), b = 1 × 10^-2(mol L^-1), b_ref = 1.0 × 10^-3(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rubrene. used solvent k_d = 4.2 × 10⁴ s^-1.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

b = 3.3 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.0033 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: 9-Methylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

b = 1.2 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.0012 mol/L.