9-Phenylanthracene Singlet oxygen

Stevens, B.; Perez, S.R.; Ors, J.A.
J. Am. Chem. Soc. 96, 6846-6850 (1974)

Reaction: 9-Phenylanthracene + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₆H₆

k = 4.2 × 10⁵(L mol^-1 s^-1), b = 1.0 × 10^-1(mol L^-1), b_ref = 1.0 × 10^-3(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rubrene. meas. k_d/k = 0.10 mol/L. used solvent k_d = 4.2 × 10⁴ s^-1.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: 9-Phenylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

b = 7.4 × 10^-4(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 7.4-4 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: 9-Phenylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

b = 7.2 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 7.2 × 10^-3 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: 9-Phenylanthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂

b = 8.4 × 10^-4(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 8.4 × 10^-4 mol/L.