26938 37802 SingOx/Table4/SOX_4_

2-(Phenoxymethylidene)adamantane
Singlet oxygen

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: 1-PrOH

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methylphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Benzene

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Benzene

k/k_reference = 2 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 0.2.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Chlorophenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Benzene

k/k_reference = 5
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(3-Chlorophenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Benzene

k/k_reference = 10
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 10.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(3-Chlorophenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Methylene chloride

k/k_reference = 3
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 3.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Chlorophenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Methylene chloride

k/k_reference = 2
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 2.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: CH₂Cl₂

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methylphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Methylene chloride

k/k_reference = 6.7 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.67.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: CH₃CN

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Ethyl acetate

k/k_reference = 2 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 0.2.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: Acetone

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: EtOH

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: MeOH

k/k_reference = 5 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.5.

Jefford, C.W.; Grant, H.G.; Jaggi, D.; Boukouvalas, J.; Kohmoto, S.
Helv. Chim. Acta 67, 2210-2217 (1984)

Reaction: 2-(Phenoxymethylidene)adamantane + ¹O₂^* Ž products
Reference Reaction: 2-(4-Methoxyphenoxymethylidene)adamantane + ¹O₂^* Ž
Solvent: THF

k/k_reference = 2 × 10^-1
T = 283K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 0.2.

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2-(Phenoxymethylidene)adamantane Singlet oxygen

2-(Phenoxymethylidene)adamantane
Singlet oxygen