Furfurylamine Singlet oxygen

Young, R.H.; Martin, R.L.; Chinh, N.; Mallon, C.; Kayser, R.H.
Can. J. Chem. 50, 932-938 (1972)

Reaction: Furfurylamine + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

b = 3.0 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Methylene Blue; Indicator = 1,3-Diphenylisobenzofuran. meas. k_d/k = 0.030 mol/L.

Koch, E.
Tetrahedron 24, 6295-6318 (1968)

Reaction: Furfurylamine + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

Activation energy = 2.9(kJ mol^-1)
b = 9.0 × 10^-3(mol L^-1), T = 293K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 9.0 × 10^-3 mol/L.