4,4'-(4,7-Dihydro-5,6-dimethylisobenzofuran-1,3-diyl)bis(benzene-p-decanoate ion)
Singlet oxygen
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4,4'-(4,7-Dihydro-5,6-dimethylisobenzofuran-1,3-diyl)bis(benzene-p-decanoate ion)
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Giraud, M.; Valla, A.; Bazin, M.; Santus, R.; Momzikoff, A.
J. Chem. Soc., Chem. Commun., 1147-1148 (1982)
Reaction: 4,4'-(4,7-Dihydro-5,6-dimethylisobenzofuran-1,3-diyl)bis(benzene-p-decanoate ion) + 1O2* ®
products
Reference Reaction: DL-Histidine + 1O2* ®
Solvent: D2O, 95%, H2O, 5%
kreact = 3 × 108(L mol-1 s-1), kreference = 5 × 107(L mol-1 s-1), pH = 10
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: >398 nm
Photosensitizer = Hematoporphyrin IX.
Added solute 1 × 10-4.
[Sensitizer] = 5 × 10-6 (mol L-1).
Giraud, M.; Valla, A.; Bazin, M.; Santus, R.; Momzikoff, A.
J. Chem. Soc., Chem. Commun., 1147-1148 (1982)
Reaction: 4,4'-(4,7-Dihydro-5,6-dimethylisobenzofuran-1,3-diyl)bis(benzene-p-decanoate ion) + 1O2* ®
products
Reference Reaction: DL-Histidine + 1O2* ®
Solvent: H2O
kreact = 7.1 × 107(L mol-1 s-1), kreference = 5 × 107(L mol-1 s-1), pH = 10
Experimental method: Photolysis
Analytical method: HPLC
Data type: Relative value measured by steady state method
Excitation wavelength: >398 nm
Photosensitizer = Hematoporphyrin IX.
Added solute 1 × 10-4.
[Sensitizer] = 5 × 10-6 (mol L-1).