1,3-Diphenylisobenzofuran Singlet oxygen

Bouirig, H.; Eloy, D.; Jardon, P.
J. Chim. Phys. Phys.-Chim. Biol. 89, 1391-1411 (1992)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (ves)

k = 2.3 × 10¹⁰(L mol^-1 s^-1), b = 1.1 × 10^-6(mol L^-1), pH = 7, T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 559 nm

Photosensitizer = Hypericin; vesicles contg. 5 × 10^-4 mol L^-1 DPPC. used solvent k_d = 2.5 × 10⁴ s^-1.

Venkatesan, R.; Periasamy, N.; Srivastava, T.S.
Proc. - Indian Acad. Sci., Chem. Sci. 104, 713-722 (1992)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: DMF

k = 1.1 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Hematoporphyrin dimethyl ester. used solvent k_d = 1.0 × 10⁵ s^-1.

Jiang, X.-F; Wang, D.-Y.
Acta Chim. Sin. (Huaxue Xuebao) 50, 391-396 (1992)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 5.1 × 10⁹(L mol^-1 s^-1), T = 303K

Experimental method: Photolysis
Data type: Derived from steady state measurements

Photosensitizer = HA; Quencher = Azide ion; micellar soln. contg. 2.9 × 10^-4 mol L^-1 SDS. used solvent k_d = 5.0 × 10⁵ s^-1. k = 6.2 × 10⁹ and 2.3 × 10⁹ L/(mol·s) in soln. contg. TDPB and Triton X-100, resp. Use Azide ion as quencher.

Bouirig, H.; Eloy, D.; Jardon, P.
J. Chim. Phys. Phys.-Chim. Biol. 89, 1391-1411 (1992)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (ves)

k = 2.5 × 10¹⁰(L mol^-1 s^-1), b = 1 × 10^-5(mol L^-1), pH = 7, T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 559 nm

Photosensitizer = Hypericin; vesicles contg. 5 × 10^-4 mol L^-1 DPPC. used solvent k_d = 2.5 × 10⁵ s^-1.

Okamoto, M.
J. Phys. Chem. 96, 245-248 (1992)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: HMN

Volume of activation = -6(cm³ mol^-1), Pressure range 0.1 to 400
k = 3.9 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Reddi, E.; Valduga, G.; Rodgers, M.A.J.; Jori, G.
Photochem. Photobiol. 54, 633-637 (1991)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 8.8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 532 nm

Photosensitizer = Hematoporphyrin IX.

Okamoto, M.; Tanaka, F.; Teranishi, H.
J. Phys. Chem. 94, 669-672 (1990)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: n-C₆H₁₄

Volume of activation = -14(cm³ mol^-1), Pressure range 0.1 to 400
k = 2.6 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Anthracene; see also [92OKA].

Shereshovets, V.V.; Kabalnova, N.N.; Komissarov, V.D.; Mavrodiev, V.K.; Lerman, B.M.; Belogaeva, T.A.; Tolstikov, G.A.
React. Kinet. Catal. Lett. 41, 251-256 (1990)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Cl, 90%, 2-PrOH, 10%

k = 7 × 10⁸(L mol^-1 s^-1), T = 273K

Experimental method: Chemical reaction
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

used solvent k_d = 4.1 × 10⁴ s^-1; ¹O₂* from hydrotrioxide, e.g. (CH₃)₂C(OH)OOOH.

Okamoto, M.; Tanaka, F.; Teranishi, H.
J. Phys. Chem. 94, 669-672 (1990)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

Volume of activation = -15(cm³ mol^-1), Pressure range 0.1 to 400
k = 1.4 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Anthracene; see also [92OKA].

Okamoto, M.; Tanaka, F.; Teranishi, H.
J. Phys. Chem. 94, 669-672 (1990)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MCH

Volume of activation = -19(cm³ mol^-1), Pressure range 0.1 to 400
k = 3.7 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Anthracene; see also [92OKA].

Okamoto, M.; Tanaka, F.; Teranishi, H.
J. Phys. Chem. 94, 669-672 (1990)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

Volume of activation = -20(cm³ mol^-1), Pressure range 0.1 to 400
k = 7.2 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Anthracene; see also [92OKA].

Lagorio, M.G.; Dicelio, L.E.; San Roman, E.A.; Braslavsky, S.E.
J. Photochem. Photobiol., B 3, 615-624 (1989)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: DMSO

k ³2.8 × 10⁸(L mol^-1 s^-1), b = 1.2 × 10^-4(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Copper(II) tetracarboxyphthalocyanine. used solvent k_d = 3.3 × 10⁴ s^-1. [O₂] = O₂.

Gorman, A.A.; Hamblett, I.; Lambert, C.; Spencer, B.; Standen, M.C.
J. Am. Chem. Soc. 110, 8053-8059 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Toluene

Activation energy = -3 (7)(kJ mol^-1), Log(A) = 8.423, Enthalpy of activation = -5 (4)(kJ mol^-1), Entropy of activation = -109 (-70)(J K^-1 mol^-1), Temperature range 183 to 363 K
k = 8.9 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 532 nm

Photosensitizer = Protoporphyrin IX, dimethyl ester; pre-exciplex-equilibrium limit (and diffusion limit). [Sensitizer] = 3.6 × 10^-5 (mol L^-1).

Racinet, H.; Jardon, P.; Gautron, R.
J. Chim. Phys. Phys.-Chim. Biol. 85, 971-977 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 1.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Hypericin; BRIJ 35 micelles. [Sensitizer] = 1.3 × 10^-5 (mol L^-1). [O₂] = 1.39 × 10^-3.

Valduga, G.; Nonell, S.; Reddi, E.; Jori, G.; Braslavsky, S.E.
Photochem. Photobiol. 48, 1-5 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CH₂OH

k = 1 × 10⁹(L mol^-1 s^-1), T = 291K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 354 or 600 nm

Photosensitizer = Zinc(II) phthalocyaninebis(pyridine). used solvent k_d = 7.1 × 10⁴ s^-1. [O₂] = air.

Valduga, G.; Nonell, S.; Reddi, E.; Jori, G.; Braslavsky, S.E.
Photochem. Photobiol. 48, 1-5 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CH₂OH

k = 1.1 × 10⁹(L mol^-1 s^-1), T = 291K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 354 or 600 nm

Photosensitizer = Zinc(II) phthalocyaninebis(pyridine). [O₂] = air.

Valduga, G.; Nonell, S.; Reddi, E.; Jori, G.; Braslavsky, S.E.
Photochem. Photobiol. 48, 1-5 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (ves)

k = > 3 × 10⁶(L mol^-1 s^-1), T = 291K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 354 or 600 nm

Photosensitizer = Zinc(II) phthalocyaninebis(pyridine); unilamellar DPPC vesicles. [O₂] = air.

Valduga, G.; Nonell, S.; Reddi, E.; Jori, G.; Braslavsky, S.E.
Photochem. Photobiol. 48, 1-5 (1988)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (ves)

k = 1 × 10⁷(L mol^-1 s^-1), T = 291K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 354 or 600 nm

Photosensitizer = Zinc(II) phthalocyaninebis(pyridine); unilamellar DPPC vesicles. used solvent k_d = 2.5 × 10⁵ s^-1. [O₂] = air.

Carre, C.; Reichardt, C.; Lougnot, D.J.
J. Chim. Phys. Phys.-Chim. Biol. 84, 577-585 (1987)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Propylene carbonate

k = 1.0 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Carre, C.; Reichardt, C.; Lougnot, D.J.
J. Chim. Phys. Phys.-Chim. Biol. 84, 577-585 (1987)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃OH

k = 9 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Carre, C.; Reichardt, C.; Lougnot, D.J.
J. Chim. Phys. Phys.-Chim. Biol. 84, 577-585 (1987)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: 2-Methoxyethanol

k = 1.2 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Zhang, Y.; Ma, H.; Dai, J.
Kexue Tongbao (Foreign Lang. Ed.) 31, 1065-1069 (1986)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: DMSO, 75%, H₂O, 25%

k = 6.9 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 1.2 × 10⁵ s^-1. [O₂] = O₂.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Pyridine

k_react = 6.5 × 10⁸(L mol^-1 s^-1), b = 9.1 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 5.9 × 10⁴ s^-1.

Chattopadhyay, S.K.; Kumar, C.V.; Das, P.K.
J. Photochem. 24, 1-9 (1984)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₂

k = 3.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337.1 nm

Photosensitizer = 2'-Acetonaphthone. Added solute 5-50 × 10^-5.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Cyclohexane

k_react = 5.0 × 10⁸(L mol^-1 s^-1), b = 1.2 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 5.9 × 10⁴ s^-1.

Nowakowska, M.
Polym. Photochem. 4, 347-359 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Cyclohexane

k_react = 5.4 × 10⁸(L mol^-1 s^-1), b = 1.1 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 365 nm

Photosensitizer = 1,3-Diphenylisobenzofuran. used solvent k_d = 5.9 × 10⁴ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Hexane

k_react = 4.4 × 10⁸(L mol^-1 s^-1), b = 1.4 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 6.2 × 10⁴ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Toluene

k_react = 4.3 × 10⁸(L mol^-1 s^-1), b = 1.2 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 5.0 × 10⁴ s^-1.

Chattopadhyay, S.K.; Kumar, C.V.; Das, P.K.
J. Photochem. 24, 1-9 (1984)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 8.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337.1 nm

Photosensitizer = 2'-Acetonaphthone. Added solute 5-50 × 10^-5.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Benzene

k_react = 7.0 × 10⁸(L mol^-1 s^-1), b = 6.0 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 4.2 × 10⁴ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Acetone

k_react = 4.1 × 10⁸(L mol^-1 s^-1), b = 9.4 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 3.9 × 10⁴ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Ethanol

k_react = 4.3 × 10⁸(L mol^-1 s^-1), b = 1.2 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 5.3 × 10⁴ s^-1.

Chattopadhyay, S.K.; Kumar, C.V.; Das, P.K.
J. Photochem. 24, 1-9 (1984)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 8.1 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337.1 nm

Photosensitizer = 2'-Acetonaphthone. Added solute 5-50 × 10^-5.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Methanol

k_react = 6.0 × 10⁸(L mol^-1 s^-1), b = 2.4 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 1.4 × 10⁵ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Tetrahydrofuran

k_react = 5.2 × 10⁸(L mol^-1 s^-1), b = 8.4 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 4.4 × 10⁴ s^-1.

Nowakowska, M.
J. Chem. Soc., Faraday Trans. 1 80, 2119-2126 (1984)

Reaction: DPBF + ¹O₂^* ® products
Solvent: Isooctane

k_react = 4.4 × 10⁸(L mol^-1 s^-1), b = 1.1 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 5.0 × 10⁴ s^-1.

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅COCH₃

k = 9.0 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 589 nm

Photosensitizer = Methylene Blue; see also [83DAR/VID2]. Added solute 4.8 × 10^-5. [Sensitizer] = 2 × 10^-5 (mol L^-1).

Fuke, K.; Ueda, M.; Itoh, M.
J. Am. Chem. Soc. 105, 1091-1096 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₂ (mic)

k = 5.3 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: temperature changes
Data type: Absolute value measured directly
Excitation wavelength: 520 nm nm

Photosensitizer = Erythrosin dianion; reverse micelles contg. 0.04 mol L^-1 DAP and 0.1 mol L^-1 water. [Sensitizer] = 1 × 10^-5 (mol L^-1).

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅C₂H₅

k = 6.7 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 589 nm

Photosensitizer = Methylene Blue; see also [83DAR/VID2]. Added solute 4.8 × 10^-5. [Sensitizer] = 2 × 10^-5 (mol L^-1).

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅CHOHCH₃

k = 1.0 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 589 nm

Photosensitizer = Methylene Blue; see also [83DAR/VID2]. Added solute 4.8 × 10^-5. [Sensitizer] = 2 × 10^-5 (mol L^-1).

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Cl

k = 7.0 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 589 nm

Photosensitizer = Methylene Blue; see also [83DAR/VID2]. Added solute 4.8 × 10^-5. [Sensitizer] = 2 × 10^-5 (mol L^-1).

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄, 98%, CH₃OH, 2%

k = 2.9 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 589 nm

Photosensitizer = Methylene Blue; see also [83DAR/VID2]. Solvent contains 2% MeOH. Added solute 4.8 × 10^-5. [Sensitizer] = 2 × 10^-5 (mol L^-1).

Reddi, E.; Jori, G.; Rodgers, M.A.J.; Spikes, J.D.
Photochem. Photobiol. 38, 639-645 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: HCONH₂, 90%, D₂O, 10%

k = 1.1 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 532 nm

Photosensitizer = Hematoporphyrin IX. [Sensitizer] = ~2 × 10^-5 (mol L^-1). [Indicator] = 2× 10^-5-4 (mol L^-1). [O₂] = O₂.

Fuke, K.; Ueda, M.; Itoh, M.
J. Am. Chem. Soc. 105, 1091-1096 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 8.3 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: temperature changes
Data type: Absolute value measured directly
Excitation wavelength: 520 nm nm

Photosensitizer = Erythrosin dianion.

Reddi, E.; Jori, G.; Rodgers, M.A.J.; Spikes, J.D.
Photochem. Photobiol. 38, 639-645 (1983)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃OH, 90%, D₂O, 10%

k = 1.6 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 532 nm

Photosensitizer = Hematoporphyrin IX. [Sensitizer] = ~2 × 10^-5 (mol L^-1). [Indicator] = 2× 10^-5-4 (mol L^-1). [O₂] = O₂.

Gorman, A.A.; Gould, I.R.; Hamblett, I.
J. Am. Chem. Soc. 104, 7098-7104 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Cyclohexane

k = 4.5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Anthracene.

Gorman, A.A.; Gould, I.R.; Hamblett, I.
J. Am. Chem. Soc. 104, 7098-7104 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Toluene

k = 6.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Anthracene.

Gorman, A.A.; Gould, I.R.; Hamblett, I.
J. Am. Chem. Soc. 104, 7098-7104 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Acetonitrile

k = 1.1 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Anthracene.

Gorman, A.A.; Gould, I.R.; Hamblett, I.
J. Am. Chem. Soc. 104, 7098-7104 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Acetone

k = 6.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Anthracene.

Rodgers, M.A.J.; Bates, A.L.
Photochem. Photobiol. 35, 473-477 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 6.2 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone; micellar soln. contg. 4.0 × 10^-2 mol L^-1 DDAB. Added solute (2.5-10) × 10^-5.

Gorman, A.A.; Gould, I.R.; Hamblett, I.
J. Am. Chem. Soc. 104, 7098-7104 (1982)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol

k = 8.1 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Anthracene.

Peters, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 103, 6759-6761 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆D₆

k = 2.8 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone. Added solute (1-7)e-5. [Sensitizer] = ~ 1 × 10^-3 (mol L^-1).

Peters, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 103, 6759-6761 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 6.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone. Added solute (1-7)e-5. [Sensitizer] = ~ 1 × 10^-3 (mol L^-1).

Peters, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 103, 6759-6761 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 1.3 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone. Added solute (1-7)e-5. [Sensitizer] = ~ 1 × 10^-3 (mol L^-1).

Peters, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 103, 6759-6761 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃COCH₃

k = 1.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone. Added solute (1-7)e-5. [Sensitizer] = ~ 1 × 10^-3 (mol L^-1).

Peters, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 103, 6759-6761 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 4.9 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone. Added solute (1-7)e-5. [Sensitizer] = ~ 1 × 10^-3 (mol L^-1).

Lindig, B.A.; Rodgers, M.A.J.
Photochem. Photobiol. 33, 627-634 (1981)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 1.0 × 10⁹(L mol^-1 s^-1), pH = 7.4

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = Methylene Blue; micellar soln. contg. 0.1 mol L^-1 SDS; k = 6.7 × 10⁸ L/(mol·s) in soln. contg. 0.1 mol L^-1 CTAB. Added solute 2.3 × 10^-5. [Sensitizer] = 2.6 × 10^-5 (mol L^-1).

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 35B, 107-111 (1980)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₂ (mic)

k = 5.3 × 10⁸(L mol^-1 s^-1), T = 313K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Fluorescein dianion; DAP reverse micelles. used solvent k_d = 5.9 × 10⁴ s^-1.

Ivanov, V.B.; Kuprashvili, B.G.; Edilashvili, I.L.
Khim. Vys. Energ. 14, 280-282 (1980)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Hexane

k = 1.2 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Data type: Derived from steady state measurements
Excitation wavelength: 313 nm

Photosensitizer = Anthracene. used solvent k_d = 3 × 10⁴ s^-1. Added solute 1 × 10^-5. [O₂] = 3.7 × 10^-4.

Matheson, I.B.C.; Massoudi, R.
J. Am. Chem. Soc. 102, 1942-1948 (1980)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 1.3 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue; micellar soln. contg. 0.1 mol L^-1 SDS. k = 3.9 × 10⁹ L mol^-1 s^-1 at [O₂] = 0.122 mol L^-1.

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 35B, 107-111 (1980)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 7.8 × 10⁸(L mol^-1 s^-1), T = 313K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Fluorescein dianion. used solvent k_d = 1.4 × 10⁵ s^-1.

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 34B, 339-343 (1979)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₂

k = 5.3 × 10⁸(L mol^-1 s^-1), T = 303K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 338 nm

Photosensitizer = Pyrene. used solvent k_d = 5.9 × 10⁴ s^-1. Added solute 5 × 10^-5. [Sensitizer] = 1 × 10^-5 (mol L^-1).

Gorman, A.A.; Lovering, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 101, 3050-3055 (1979)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅CH₃

Enthalpy of activation = 0(kJ mol^-1), Entropy of activation = 0.0(J K^-1 mol^-1), Temperature range 223 to 353 K
k = 8.1 × 10⁸(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Naphthalene. [Sensitizer] = 10^-2 (mol L^-1).

Krasnovsky, A.A.,Jr.
Photochem. Photobiol. 29, 29-36 (1979)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 8 × 10⁸(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

Photosensitizer = Protoporphyrin, Pheophytin a or Bacteriopheophytin a. used solvent k_d = 36 s^-1.

Krasnovsky, A.A.,Jr.; Kagan, V.E.
FEBS Lett. 108, 152-154 (1979)

Krasnovsky, A.A.,Jr.; Kagan, V.E.
Dokl. Biophys. 241-243, 147-150 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 8.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements
Excitation wavelength: 385 nm

Photosensitizer = (all-E)-Retinal. used solvent k_d = 36 s^-1. [Sensitizer] = £10^-6 (mol L^-1).

Matheson, I.B.C.; Lightner, D.A.
Photochem. Photobiol. 29, 933-935 (1979)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₂FCClF₂

k = 9 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: ? nm

high pressure O₂.

Matheson, I.B.C.; Lightner, D.A.
Photochem. Photobiol. 29, 933-935 (1979)

Reaction: DPBF + ¹O₂^* ® products
Solvent: CCl₂FCClF₂

k_react = 5.0 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 1060 nm

high pressure O₂; used k_O2 = 2.5 × 10³ L mol^-1 s^-1.

Lindig, B.A.; Rodgers, M.A.J.
J. Phys. Chem. 83, 1683-1688 (1979)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 1.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 530 nm

Photosensitizer = Methylene Blue; micellar soln. contg. 0.1 mol L^-1 SDS. k = 6.7 × 10⁸ L/(mol·s) in soln. contg. 0.1 mol L^-1 CTAB. Rates also reported for micellar solutions contg. Igepal CO-630, Igepal CO-660, Brij 35, and Na laurate. Added solute 1.0-7.0 × 10^-5. [Sensitizer] = 1.1 × 10^-3 (mol L^-1).

Gorman, A.A.; Lovering, G.; Rodgers, M.A.J.
J. Am. Chem. Soc. 100, 4527-4532 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 9.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Np, An, BP, Benzil.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 1.1 × 10⁸(L mol^-1 s^-1), b = 1.2 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 1.4 × 10³ s^-1.

Furue, H.; Russell, K.E.
Can. J. Chem. 56, 1595-1601 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄, 99%, MeOH, 1%

k = 7.3 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue; Solvent contains 1% MeOH; k = 4.8 × 10⁸, 5.4 × 10⁸, 5.2 × 10⁸, 6.0 × 10⁸, 2.5 × 10⁸ L/(mol·s) with 2, 3, 4, 5, and 6% MeOH, resp.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 1.6 × 10⁹(L mol^-1 s^-1), b = 1.0 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 1.6 × 10⁴ s^-1.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 1.1 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CHCl₂

k = 6.0 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CHCl₂

k = 1.0 × 10⁹(L mol^-1 s^-1), b = 1.5 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 1.5 × 10⁴ s^-1.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 9.0 × 10⁸(L mol^-1 s^-1), b = 1.0 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 9.0 × 10³ s^-1.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 7.0 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₂CHCl₂

k = 4.4 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₂CHCl₂

k = 5.9 × 10⁸(L mol^-1 s^-1), b = 1.4 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; used solvent k_d = 8.3 × 10³ s^-1.

Gorman, A.A.; Rodgers, M.A.J.
Chem. Phys. Lett. 55, 52-54 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O (mic)

k = 8.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 337 nm

Photosensitizer = 2'-Acetonaphthone; micellar soln. contg. 0.1 mol L^-1 SDS.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 1.3 × 10⁹(L mol^-1 s^-1), b = 6.5 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Eosin dianion. used solvent k_d = 8.3 × 10⁴ s^-1.

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 33B, 622-627 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 2.2 × 10¹⁰(L mol^-1 s^-1), T = 313K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Pyrene; Quencher = Azide ion; SDS micelles. used solvent k_d = 5.0 × 10⁵ s^-1. k = 2.8 × 10¹⁰ L/(mol·s) in DTAC micelles. Use Azide ion as quencher.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 4.2 × 10⁹(L mol^-1 s^-1), b = 1.2 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Eosin dianion; SDS micelles. used solvent k_d = 5.0 × 10⁵ s^-1.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 4.7 × 10⁹(L mol^-1 s^-1), b = 1.1 × 10^-4(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; SDS micelles. used solvent k_d = 5 × 10⁵ s^-1.

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 33B, 622-627 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 7.8 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Pyrene; Quencher = Azide ion. used solvent k_d = 1.4 × 10⁵ s^-1. Use Azide ion as quencher.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 1.6 × 10⁹(L mol^-1 s^-1), b = 7.1 × 10^-5(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Erythrosin dianion or Methylene Blue. used solvent k_d = 1.1 × 10⁵ s^-1.

Usui, Y.; Tsukada, M.; Nakamura, H.
Bull. Chem. Soc. Jpn. 51, 379-384 (1978)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 1.6 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Gorman, A.A.; Lovering, G.; Rodgers, M.A.J.
Photochem. Photobiol. 23, 399-403 (1976)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O (mic)

k = 5.2 × 10⁹(L mol^-1 s^-1), b = 9.7 × 10^-5(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; SDS micelles. used solvent k_d = 5 × 10⁵ s^-1.

Schmidt, H.; Rosenkranz, P.
Z. Naturforsch., C, Biosci. 31, 29-39 (1976)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 1.0 × 10⁹(L mol^-1 s^-1), b = 1.1 × 10^-4(mol L^-1), T = 293K

Experimental method: Photolysis
Data type: Derived from steady state measurements

Photosensitizer = Acridine Orange. used solvent k_d = 1.1 × 10⁵ s^-1.

Foote, C.S.; Ching, T.-Y.
J. Am. Chem. Soc. 97, 6209-6214 (1975)

Reaction: DPBF + ¹O₂^* ® products
Solvent: CHCl₃, 90%, MeOH, 10%

k = 5 × 10⁸(L mol^-1 s^-1), b = 8 × 10^-5(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; Used solvent k_d = 3.9 × 10⁴ s^-1 and quantum yield of intersystem crossing for sensitizer = 0.66.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: 1-BuOH

k/k_reference = 17
k_react = 8.3 × 10⁸(L mol^-1 s^-1), k_reference = 5.0 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; The same value was obtained by steady state measurements using solvent k_d = 5.2 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: tert-BuOH

k/k_reference = 17
k_react = 6.2 × 10⁸(L mol^-1 s^-1), k_reference = 3.6 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: tert-BuOH

k = 2.3 × 10⁸(L mol^-1 s^-1), b = 1 × 10^-4(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH. used solvent k_d = 3.0 × 10⁴ s^-1.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Epibromohydrin

k = 7.8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: C₅H₅N

k/k_reference = 7.9
k_react = 4.8 × 10⁸(L mol^-1 s^-1), k_reference = 6.1 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₅H₅N

k ~5.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 583 nm

Photosensitizer = Rose Bengal dianion; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: c-C₆H₁₁OH

k/k_reference = 12
k_react = 6.5 × 10⁸(L mol^-1 s^-1), k_reference = 5.3 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₁OH

k ~ 1 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 2 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 6.3 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Br

k = 5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 5 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 1.3 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Methyl benzoate

k = 4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 2.8 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 2.5 × 10⁴ s^-1; Solvent contained 1% MeOH.

Stevens, B.; Perez, S.R.; Ors, J.A.
J. Am. Chem. Soc. 96, 6846-6850 (1974)

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₆H₆

k/k_reference = 17
k_react = 7.0 × 10⁸(L mol^-1 s^-1), b = 6.0 × 10^-5(mol L^-1), k_reference = 4.2 × 10⁷(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rubrene.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k ~ 4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 5 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 3.8 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: C₆H₆, 80%, MeOH, 20%

k_react = 1.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; ref. k not given. k = 2 × 10⁹ L/(mol·s) was obtained by steady state measurements using solvent k_d = 3.8 × 10⁴ s^-1.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₃CH₂OH

k ~2.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 2.6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH. The same value for k was obtained in CCl₄ contg. 6, 10, 14 and 17% MeOH

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: CF₃CH₂OH

k_react = 1.2 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; ref. k not given. Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CF₃CH₂OH

k = 6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 2 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 2.3 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: CH₂Cl₂

k/k_reference = 7.3
k_react = 6.3 × 10⁸(L mol^-1 s^-1), k_reference = 8.6 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂FCH₂OH

k ~ 5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 6.6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 1 × 10⁹ L/(mol·s) was obtained by steady state measurements using solvent k_d = 1.8 × 10⁴ s^-1.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 5.6
k_react = 1.1 × 10⁹(L mol^-1 s^-1), k_reference = 2.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Ethyl acetate

k = 8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: Ethyl acetate

k/k_reference = 12
k_react = 3.5 × 10⁸(L mol^-1 s^-1), k_reference = 3.0 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: (CH₃)₂CO

k = 6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 5 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 2.4 × 10⁴ s^-1.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: (CH₃)₂CO

k/k_reference = 9.4
k_react = 1.7 × 10⁹(L mol^-1 s^-1), k_reference = 1.8 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: CHCl₃

k/k_reference = 2.9
k_react = 1.4 × 10⁸(L mol^-1 s^-1), k_reference = 4.9 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 3.6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₂CH₂OH

k = 5.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 1.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 12
k_react = 1.4 × 10⁹(L mol^-1 s^-1), k_reference = 1.1 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; k = 1.3 × 10⁹ L/(mol·s) was obtained by steady state measurements using solvent k_d = 9.0 × 10⁴ s^-1.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: 2-PrOH

k/k_reference = 13
k_react = 6.1 × 10⁸(L mol^-1 s^-1), k_reference = 4.8 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: 2-PrOH

k = 1.5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 5 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 5.0 × 10⁴ s^-1; Solvent contained 1% MeOH.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: THF

k/k_reference = 11
k_react = 8.3 × 10⁸(L mol^-1 s^-1), k_reference = 7.5 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: THF

k = 5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 583 nm

Photosensitizer = Rose Bengal dianion.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: 2,5-Diphenylfuran + ¹O₂^* ®
Solvent: Dioxane

k/k_reference = 11
k_react = 3.1 × 10⁸(L mol^-1 s^-1), k_reference = 2.7 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion.

Brewer, D.R.,III
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1974, 694p.

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Dioxane

k = 8.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV emission
Data type: Absolute value measured directly
Excitation wavelength: 583 nm

Photosensitizer = Rose Bengal dianion.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: 1-BuOH

k = 8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: tert-BuOH

k = 5.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; Solvent contained 1% MeOH.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₅H₅N

k = 2.1 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Br, 80%, MeOH, 20%

k = 7.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue; k = 5 × 10⁸ L/(mol·s) was obtained by steady state measurements using solvent k_d = 4.3 × 10⁴ s^-1.

Farmilo, A.; Wilkinson, F.
Photochem. Photobiol. 18, 447-450 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 2 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Anthracene.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆, 80%, MeOH, 20%

k = 9 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Flood, J.; Russell, K.E.; Wan, J.K.S.
Macromolecules 6, 669-671 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 98%, MeOH, 2%

k = 3.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Ethylene glycol

k = 1.5 × 10⁹(L mol^-1 s^-1), b = 3.2 × 10^-4(mol L^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue or Rose Bengal.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 1.3 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue or Rose Bengal.

Olmsted, J.,III; Akashah, T.
J. Am. Chem. Soc. 95, 6211-6215 (1973)

Reaction: DPBF + ¹O₂^* ® products
Solvent: MeOH

k_react = 6.1 × 10⁸(L mol^-1 s^-1), b = 2.3 × 10^-4(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; used intersystem crossing yield (RB) = 0.76. used solvent k_d = 1.4 × 10⁵ s^-1.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH, 50%, H₂O, 50%

k = 5.1 × 10⁹(L mol^-1 s^-1), b = 5.5 × 10^-5(mol L^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Rose Bengal or Methylene Blue.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol, 50%, Ethylene glycol, 50%

k = 1.9 × 10⁹(L mol^-1 s^-1), b = 6.3 × 10^-5(mol L^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue or Rose Bengal.

Young, R.H.; Brewer, D.; Keller, R.A.
J. Am. Chem. Soc. 95, 375-379 (1973)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: Dioxane

k = 1.2 × 10⁹(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 610 nm

Photosensitizer = Methylene Blue.

Merkel, P.B.; Kearns, D.R.
J. Am. Chem. Soc. 94, 7244-7253 (1972)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 8 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Merkel, P.B.; Kearns, D.R.
Chem. Phys. Lett. 12, 120-122 (1971)

Reaction: DPBF + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 7.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 694 nm

Photosensitizer = Methylene Blue.

Wilson, T.
J. Am. Chem. Soc. 88, 2898-2902 (1966)

Reaction: DPBF + ¹O₂^* ® products
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₅H₅N

k/k_reference = 22

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rubrene. Meas. k/k_ref = 22.