Aniline Singlet oxygen

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 35B, 107-111 (1980)

Reaction: C₆H₅NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: c-C₆H₁₂ (mic)

k = 3.9 × 10⁷(L mol^-1 s^-1), T = 313K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Fluorescein dianion; Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 5.9 × 10⁴ s^-1; DAP reverse micelles.

Miyoshi, N.; Tomita, G.
Z. Naturforsch., Teil B 35B, 107-111 (1980)

Reaction: C₆H₅NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 2.0 × 10⁹(L mol^-1 s^-1), T = 313K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Fluorescein dianion; Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 1.4 × 10⁵ s^-1.;

Bartlett, P.D.; Mendenhall, G.D.; Durham, D.L.
J. Org. Chem. 45, 4269-4271 (1980)

Reaction: C₆H₅NH₂ + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: MeOH, 67%, C₆H₆, 33%

k/k_reference = 9.1
T = 298K

Experimental method: Chemical reaction
Data type: Relative value measured by steady state method

¹O₂* from (PhO)₃PO₃; meas. k/k_ref = 9.1.

Pouyet, B.; Chapelon, R.
C. R. Hebd. Seances Acad. Sci., Ser. C 272, 1753-1756 (1971)

Reaction: C₆H₅NH₂ + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: EtOH

k/k_reference = 3.0

Experimental method: Photolysis
Data type: Derived from steady state measurements

Photosensitizer = Eosin, Erythrosin, or Rose Bengal; meas. k/k_ref = 3.0.

Pouyet, B.; Chapelon, R.
C. R. Hebd. Seances Acad. Sci., Ser. C 272, 1753-1756 (1971)

Reaction: C₆H₅NH₂ + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: EtOH

k/k_reference = 2.7

Experimental method: Photolysis
Data type: Derived from steady state measurements

Self-sensitized; meas. k/k_ref = 2.7.