Inorganic Radicals

One-electron transfer oxidations and reductions by inorganic radicals are important in atmospheric and industrial processes. Rate constants have been compiled for reactions of various inorganic radicals produced by radiolysis or photolysis, as well as by other chemical means, in aqueous solutions. Radicals have been derived from carbonate, azide, nitrite, nitrate, phosphite, phosphate, sulfite, sulfate, selenite, thiocyanate, chloride, bromide, iodide and formate ion. Rate constants for reactions of ozone and various radicals from N, S, Se, Cl, Br and I compounds are also included.

Recent data have been compiled and evaluated and added, along with these data, to the NDRL/NIST Solution Kinetics Database.

Published by:

P. Neta, R.E. Huie and A.B. Ross
J. Phys. Chem. Ref. Data, 17 1027-1284 (1988) __ Ordering info.

-- -- --

Work jointly supported by:

Office of Basic Energy Sciences
United States Department of Energy

Standard Reference Data
National Institute of Standards and Technology