NDRL Radiation Chemistry Data Center Recent Papers in Radiation and Photochemistry 11/23/99 # 99_22

Kinetics	Optical Spectra	Thermodynamics
ESR Studies	Excited States	Photochemistry
Radiation Chemistry	Related Experimental Studies	Multiphase Systems
Polymers	Biological and Medical Aspects	Solar Energy
Industrial and Environmental Applications	Theoretical Studies	Reviews

Kinetics

Kinetics of nucleophilic attack on coordinated organic moieties. Part 32. Synthetic and mechanistic studies of the reaction of iodide ion with [([eta]⁵-dienyl)Fe(CO)₃]⁺ cations (dienyl = C₆H₇, 2-MeOC₆H₆, C₇H₉).
Siu, A.F.H., David, D.A., Kane-Maguire, L.A.P., Pyne, S.G., Lambrecht, R.H., J. Coord. Chem. 46(2): 125-43 (1998).

Luminescence of free and self-trapped excitons in J-aggregates of quino-2-monomethine cyanine.
Malyukin, Y.V., Katrich, G.S., Ainbund, M.R., Kemnitz, K., Opt. Spektrosk. 85(4): 577-80 (1998).

Kinetics of proton transfer reactions involving carbon.
Wirz, J., Pure Appl. Chem. 70(11): 2221-32 (1998).

Hydroxylation of aliphatic hydrocarbons with m-chloroperbenzoic acid catalyzed by electron-deficient iron(III) porphyrin complexes.
Lim, M.H., Lee, Y.J., Goh, Y.M., Nam, W., Kim, C., Bull. Chem. Soc. Jpn. 72(4): 707-13 (1999).

Propagating radicals in photo-initiated polymerization as detected by time-resolved CW- and FT-ESR spectroscopy.
Mizuta, Y., Morishita, N., Kuwata, K., Chem. Lett. (4): 311-2 (1999).

Kinetics and mechanism of aqueous oxidation of H₂S by Fe⁺³.
Tekin, T., Boyabat, N., Bayramoglu, M., Int. J. Chem. Kinet. 31(5): 331-5 (1999).

Rate constants of the thermal cis-trans isomerization of azobenzene dyes in solvents, acetone/water mixtures, and in microheterogeneous surfactant solutions.
Gille, K., Knoll, H., Quitzsch, K., Int. J. Chem. Kinet. 31(5): 337-50 (1999).

Kinetics of oxidation and comproportionation reactions involving an oxammonium ion, benzyl alcohol and methyltrioxorhenium(VII).
Zauche, T.H., Espenson, J.H., Int. J. Chem. Kinet. 31(5): 381-5 (1999).

Far-UV time-resolved circular dichroism detection of electron-transfer-triggered cytochrome c folding.
Chen, E.F., Wittung-Stafshede, P., Kliger, D.S., J. Am. Chem. Soc. 121(16): 3811-7 (1999).

Nucleic acid oxidation mediated by naphthalene and benzophenone imide and diimide derivatives: Consequences for DNA redox chemistry.
Rogers, J.E., Kelly, L.A., J. Am. Chem. Soc. 121(16): 3854-61 (1999).

Radical addition rate constants to acrylates and oxygen: [alpha]-hydroxy and [alpha]-amino radicals produced by photolysis of photoinitiators.
Jockusch, S., Turro, N.J., J. Am. Chem. Soc. 121(16): 3921-5 (1999).

Mechanistic studies of the azomethine ylide-forming photoreactions of N-(silylmethyl)phthalimides and N-phthaloylglycine.
Takahashi, Y., Miyashi, T., Yoon, U.C., Oh, S.W., Mancheno, M., Su, Z.Y., Falvey, D.F., Mariano, P.S., J. Am. Chem. Soc. 121(16): 3926-32 (1999).

Mechanism of displacement of alkanes from photogenerated (alkane) Cr(CO)₅ complexes.
Dobson, G.R., Zhang, S.L., J. Coord. Chem. 47(3): 409-16 (1999).

The Cp₂TiPh-mediated reductive radical cyclization of cyanoketones and related reactions. Efficient trapping of ketyl radicals by Cp₂TiPh-coordinated polar multiple bonds.
Yamamoto, Y., Matsumi, D., Hattori, R., Itoh, K., J. Org. Chem. 64(9): 3224-9 (1999).

Solvent effects on the antioxidant activity of vitamin E.
Valgimigli, L., Banks, J.T., Lusztyk, J., Ingold, K.U., J. Org. Chem. 64(9): 3381-3 (1999).

Laser flash photolysis studies of radical-radical reaction kinetics: The HO₂ + IO reaction.
Cronkhite, J.M., Stickel, R.E., Nicovich, J.M., Wine, P.H., J. Phys. Chem. A 103(17): 3228-36 (1999).

Rate coefficients for the reactions of OH and OD with HCl and DCl between 200 and 400 K.
Battin-Leclerc, F., Kim, I.K., Talukdar, R.K., Portmann, R.W., Ravishankara, A.R., J. Phys. Chem. A 103(17): 3237-44 (1999).

Do the charge-transfer complexes of 1,2,4,5-tetracyanobenzene with arenes serve as a probe for surveying chemical properties inside the cavities of faujasite zeolites? Time-resolved and steady-state spectroscopic studies.
Hashimoto, S., Hagiwara, N., Asahi, T., Masuhara, H., Langmuir 15(9): 3123-33 (1999).

Synthesis, molecular structure and radical scavenging effect of octanuclear thiolate zinc complex [NMe₄]₂[(C-[mu]⁴-S)([mu]-SCH₂Ph)₁₂S₄Zn₈].
Guo, S.L., Ding, E., Chen, H., Yin, Y.Q., Li, X.J., Polyhedron 18(5): 735-40 (1999).

Solvent effects on quenching of partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes with viologens.
Suzuki, M., Yokoyama, N., Kimura, M., Hanabusa, K., Shirai, H., React. Funct. Polym. 40(2): 97-105 (1999).

Kinetic studies on the single electron transfer reaction between 2,2,6,6-tetramethylpiperidine oxoammonium ions and phenothiazines: the application of Marcus theory.
Wu, L.M., Guo, X., Wang, J., Guo, Q.X., Liu, Z.L., Liu, Y.C., Sci. China, Ser. B: Chem. 42(2): 138-44 (1999).

Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl₃-catalyzed oxidation of C-H bonds with tert-butyl hydroperoxide.
Merrigan, S.R., Le Gloahec, V.N., Smith, J.A., Barton, D.H.R., Singleton, D.A., Tetrahedron Lett. 40(20): 3847-50 (1999).

Low-temperature photophysics of permethylated n-heptasilane: The borderline between excitation localization and delocalization in a conjugated chain.
Raymond, M.K., Magnera, T.F., Zharov, I., West, R., Dreczewski, B., Nozik, A.J., Sprague, J.R., Ellingson, R.J., Michl, J., Appl. Fluoresc. Chem., Biol. Med., W. Rettig (ed.), Springer, Berlin, Germany, 1999, p.79-99

Optical Spectra

Photoluminescence properties of erbium doped III-V semiconductors.
Culp, T.D. Ph.D., Thesis, Univ. Wisconsin, Madison, WI, 1998, 275p.

Applications of laser-induced fluorescence excitation emission matrix spectroscopy for the analysis of PAHs.
Hart, S.J. Ph.D., Thesis, Tufts Univ., Medford, MA, 1998, 393p.

Association behavior of 1-pyrenyl pendants introduced into the papain active site.
Sakurai, T., Nojima, K.M., Watanabe, K., Kubo, K., Inoue, H., Bull. Chem. Soc. Jpn. 72(4): 757-64 (1999).

A mercurated azobenzene complex for photoswitching between trans and cis forms.
Barigelletti, F., Ghedini, M., Pucci, D., LaDeda, M., Chem. Lett. (4): 297-8 (1999).

Interaction between excitons of CuCl microcrystals and intrinsic color centers of matrix in photochromic glass.
Kraevskii, S.L., Solinov, V.F., Zyabnev, A.M., Glass Phys. Chem. (Transl. of Fiz. Khim. Stekla) 25(2): 151-8 (1999).

Electronic states of a photochromic 2-(2,4-dinitrobenzyl) pyridine single crystal.
Takeda, J., Shinohara, S., Eguchi, N., Ohishi, S., Kurita, S., Kodaira, T., J. Phys. Soc. Jpn. 68(4): 1423-9 (1999).

Influence of different environments on the excited-state proton transfer and dual fluorescence of fisetin.
Guharay, J., Dennison, S.M., Sengupta, P.K., Spectrochim. Acta, Part A 55A(5): 1091-9 (1999).

Thermodynamics

Dynamic effects in long-distance biological electron transfer reactions.
Medvedev, E.S., Stuchebrukhov, A.A., Pure Appl. Chem. 70(11): 2201-10 (1998).

Synthesis and photochemical properties of ruthenium-cobalt and ruthenium-nickel dinuclear complexes.
Komatsuzaki, N., Himeda, Y., Hirose, T., Sugihara, H., Kasuga, K., Bull. Chem. Soc. Jpn. 72(4): 725-31 (1999).

Charge-transfer adducts between donors containing chalcogens (S and Se) and di-iodine: solution studies.
Aragoni, M.C., Arca, M., Devillanova, F.A., Garau, A., Isaia, F., Lippolis, V., Verani, G., Coord. Chem. Rev. 184: 271-90 (1999).

Photo-assisted electron transfer in a nickel(II) porphyrin complex: Formation of nickel(II)-porphyrin [pi]-cation radical.
Chatterjee, D., Balasubramanian, E., J. Coord. Chem. 46(4): 467-70 (1999).

Probing M-O bond cleavage in silicon and titanium bisenolate radical cations.
Schmittel, M., Burghart, A., Werner, H., Laubender, M., Sollner, R., J. Org. Chem. 64(9): 3077-85 (1999).

A novel photoinduced electron transfer reaction of N-alkylphenothiazines in carbon tetrachloride.
Guo, X., Wu, L.M., Yang, L., Liu, Y.C., Liu, Z.L., Sci. China, Ser. B: Chem. 42(2): 170-7 (1999).

ESR Studies

Use of EPR spin probe technique for detection of irradiated wheat.
Sunnetcioglu, M.M., Dadayli, D., Celik, S., Koksel, H., Appl. Radiat. Isot. 50(3): 557-60 (1999).

Deuteration effects on the in vivo EPR spectrum of the reduced secondary Photosystem I electron acceptor A₁ in cyanobacteria.
Klughammer, C., Klughammer, B., Pace, R., Biochemistry 38(12): 3726-32 (1999).

Determination by photoreduction of flip-flop kinetics of spin-labeled stearic acids across phospholipid bilayers.
Yuann, J.-M.P., Morse, R., Biochim. Biophys. Acta 1416(1-2): 135-44 (1999).

Electron spin resonance studies on photosensitized formation of hydroxyl radical by C-phycocyanin from Spirulina platensis.
Zhang, S.-P., Xie, J., Zhang, J.-P., Zhao, J.-Q., Jiang, L.-J., Biochim. Biophys. Acta 1426(1): 205-11 (1999).

Light-induced electron transfer kinetics on the surface of nanometer semiconductors - ESR study of photoreduction efficiency of TiO₂ nanometer semiconductors using 4-oxo-TEMPO as electron acceptor.
Zhou, Z., Zhang, Z., Bopuxue Zazhi 16(2): 89-96 (1999).

Investigation of the photolysis of anthraquinone in the TX-100 micelle by using TR-ESR spectrometer.
Lu, T., Cui, Z., Xun, W., Zhang, X., Bopuxue Zazhi 16(2): 103-8 (1999).

A study of electron spin polarization transfer in a system of photo-excited triplet phthalocyanine and a nitroxide radical.
Saiful, I.S.M., Fujisawa, J., Kobayashi, N., Ohba, Y., Yamauchi, S., Bull. Chem. Soc. Jpn. 72(4): 661-7 (1999).

An ESR study of a tetrasilaspirobiindane anion radical. Stereoelectronic electron-accepting effects of trialkylsilyl groups.
Setaka, W., Kabuto, C., Kira, M., Chem. Lett. (4): 317-8 (1999).

An electron spin resonance spin-trapping investigation of the free radicals formed by the reaction of mitochondrial cytochrome c oxidase with H₂O₂.
Chen, Y.-R., Gunther, M.R., Mason, R.P., J. Biol. Chem. 274(6): 3308-14 (1999).

Electron spin resonance detection of oxygen radicals released by UVA-irradiated human fibroblasts.
Souchard, J.P., Pierlot, G., Barbacanne, M.A., Charveron, M., Bonafe, J.-L., Nepveu, F., J. Chim. Phys. Phys.-Chim. Biol. 96(1): 101-9 (1999).

Formation of fullerene derivative radical by irradiation.
Kitajima, Y., Nagatani, H., Miyamoto, Y., Matsuura, K., Miyatake, Y., Arai, S., Hoshino, M., Tajima, Y., Kyoto Daigaku Genshiro Jikkensho Gakujutsu Koenkai Hobunshu 33: 195-9 (1999).

EPR study of the reaction of C₆₀ with chlorine dioxide: experimental evidence for the formation of the C₆₀ radical cation.
Sokolov, V.I., Bashilov, V.V., Timerghazin, Q.K., Avzyanova, E.V., Khalizov, A.F., Shishlov, N.M., Shereshovets, V.V., Mendeleev Commun. (2): 54-5 (1999).

Nitroarene reduction and generation of free radicals by cell-free extracts of wild-type, and nitroreductase-deficient and -enriched Salmonella typhimurium strains used in the umu gene induction assay.
Metosh-Dickey, C.A., Mason, R.P., Winston, G.W., Toxicol. Appl. Pharmacol. 154(2): 126-34 (1999).

Excited States

The influence of perchlorates on the fluorescence quenching of 9,10-dichloroanthracene by bromide salts in acetone.
Mac, M., Tokarczyk, B., Chem. Phys. Lett. 304(5-6): 309-16 (1999).

Direct measurement of excitation transfer dynamics between two trimers in C-phycocyanin hexamer from cyanobacterium Anabaena variabilis.
Zhang, J.M., Zhao, F.L., Zheng, X.G., Wang, H.Z., Chem. Phys. Lett. 304(5-6): 357-64 (1999).

Field-induced delayed photoluminescence in a conjugated polymer.
Schweitzer, B., Arkhipov, V.I., Bassler, H., Chem. Phys. Lett. 304(5-6): 365-70 (1999).

Dual excimer emission of p-terphenyl induced by [gamma]-cyclodextrin in aqueous solutions.
Pistolis, G., Chem. Phys. Lett. 304(5-6): 371-7 (1999).

Electronic relaxation and vibrational predissociation of benzene-acetylene van der Waals complexes.
Shelley, M.Y., Dai, H.L., Troxler, T., J. Chem. Phys. 110(18): 9081-90 (1999).

Single-molecule fluorescence autocorrelation experiments on pentacene: The dependence of intersystem crossing on isotopic composition.
Brouwer, A.C.J., Kohler, J., van Oijen, A.M., Groenen, E.J.J., Schmidt, J., J. Chem. Phys. 110(18): 9151-9 (1999).

Time-resolved Raman study on the photoinduced intermolecular electron-transfer reaction of biphenyl in alcohols.
Sasaki, Y., Hamaguchi, H.O., J. Chem. Phys. 110(18): 9179-85 (1999).

Experimental and theoretical studies on the intramolecular charge-transfer emission of phenyldisilanes.
Yamamoto, M., Kudo, T., Ishikawa, M., Tobita, S., Shizuka, H., J. Phys. Chem. A 103(17): 3144-54 (1999).

Zero-field splitting of the electronic ground and lowest excited triplet states of 2,2-dinaphthylcarbene in n-hexane at 1.7 K.
Kozankiewicz, B., Aloshyna, M., Gudmundsdottir, A.D., Platz, M.S., Orrit, M., Tamarat, P., J. Phys. Chem. A 103(17): 3155-62 (1999).

Quenching of excited triplet state hypericin with energy acceptors and donors and acceptors of electrons.
Darmanyan, A.P., Jenks, W.S., Eloy, D., Jardon, P., J. Phys. Chem. B 103(17): 3323-31 (1999).

Photochemistry

Manifestation of photoinduced charge-transfer process in electrooptical effect in nematic liquid crystal.
Yablonski, S.V., Oue, T., Nakayama, K., Ozaki, M., Yoshino, K., Denki Zairyo Gijutsu Zasshi 7(1): 58-60 (1998).

2,7,12,18-Tetramethyl-13,17-di(3-hydroxypropyl)porphyrin: synthesis and photosensitivity.
Chen, Z.-L., Wan, W.-Q., Chen, J.-R., Xu, D.-Y., Zhongguo Yiyao Gongye Zazhi 29(11): 501-2 (1998).

The total synthesis of mannostatin A and its analogs based on pyridinium salt photochemistry.
Ling, R. Ph.D., Thesis, Univ. Maryland, College Park, MD, 1998, 143p.

Asymmetric induction in enone-allene (2+2)photo-cycloaddition reactions: application toward the enantioselective synthesis of (+)-chebulic acid.
Shepard, M.S. Ph.D., Thesis, California Inst. Technol., Pasadena, CA, 1998, 168p.

Erratum: Photochemistry of ortho-phenoxymethyl-substituted azidobenzenes: Reassignment of the products. [Vol. 38, pg. 212 (1999)].
Bucher, G., Korth, H.G., Angew. Chem., Int. Ed. Engl. 38(9): 1170 (1999).

Photochemical cycloaromatization of non-benzenoid enediynes.
Kaneko, T., Takahashi, M., Hirama, M., Angew. Chem., Int. Ed. Engl. 38(9): 1267-8 (1999).

Photolytic and photocatalytic decomposition of bromomethanes in irradiated aqueous solutions.
Calza, P., Minero, C., Hiskia, A., Papacostantinou, E., Pelizzetti, E., Appl. Catal., B 21(3): 191-202 (1999).

Photoreactive and inactive crystals of 1-alkylthymine derivatives.
Tohnai, N., Inaki, Y., Miyata, M., Yasui, N., Mochizuki, E., Kai, Y., Bull. Chem. Soc. Jpn. 72(4): 851-8 (1999).

New photogeneration system of dihydronicotinamide and viologen radical using Ru(bpy)₃²⁺.
Suzuki, M., Kimura, M., Hanabusa, K., Shirai, H., Chem. Lett. (4): 337-8 (1999).

Erratum: Spin chemical control of photoinduced electron-transfer processes in ruthenium(II)-trisbipyridine-based supramolecular triads. [Vol. 121, pg. 1076 (1999)].
Klumpp, T., Linsenmann, M., Larson, S.L., Limoges, B.R., Burssner, D., Krissinel, E.B., Elliott, C.M., Steiner, U.E., J. Am. Chem. Soc. 121(16): 4092 (1999).

Synthesis and photoreactivity of a 2-pivaloylcyclohex-2-enone.
Ferrer, L.O., Margaretha, P., J. Chem. Res., Synop. (3): 204-5 (1999).

Radical addition reactions of fluorinated species. Part 7. Highly selective two-step synthesis of 1-(polyfluoroalkyl)ethane-1,2-diols; regioselectivity of the additions of methylated 1,3-dioxolanes to perfluoroolefins.
Cirkva, V., Paleta, O., J. Fluorine Chem. 94(2): 141-56 (1999).

The photochemical reaction of Si-substituted vinyl(ethynyl)- and diethynylsilanes with ethanethiol and its C-functional derivatives.
Vlasova, N.N., Zhila, G.Y., Yarosh, O.G., Voronkov, M.G., J. Organomet. Chem. 577(2): 157-60 (1999).

Spectrophotometric study of the photoinduced transformation of 4a,4c-dihydrodibenzophenanthrene to trans-1,2-di-(2-naphthyl)ethylene: The proof of the one-photon mechanism by the method of singular decomposition.
Razumov, V.F., Kazakov, S.P., Ryabenko, A.A., Opt. Spectrosc. (Transl. of Opt. Spektrosk.) 86(4): 537-43 (1999).

Photochemical C-H activation and ligand exchange reactions of CpRe(PPh₃)₂H₂. Phosphine dissociation is not involved.
Jones, W.D., Rosini, G.P., Maguire, J.A., Organometallics 18(9): 1754-60 (1999).

UV-induced self-assembly of the inclusion complexes formed between a long-chain photochromic spiropyran and cyclodextrins.
Sui, Q., Zhou, J.W., He, W., Li, Z.J., Wang, Y.Q., Sci. China, Ser. B: Chem. 42(2): 113-20 (1999).

Radiation Chemistry

Determination of thiobarbituric acid reactive products formed from deoxyribose in biological samples.
Turiak, G., Rosene, D., Volicer, L., Neurosci. Res. Commun. 23(3): 151-8 (1998).

Oxidation of elemental phosphorus in emulsion under [gamma]-irradiation.
Tarasova, N.P., Smetannikov, Y.V., Mikhailova, E.G., Permyakov, I.V., Dokl. Akad. Nauk 364(5): 636-9 (1999).

Influence of molecular hydrogen on the radiation-induced color centers in pure and terbium-doped aluminosilicate optical fibers.
Gerasimova, V.I., Zavorotnyi, Y.S., Rybaltovskii, A.O., Chernov, P.V., Glass Phys. Chem. (Transl. of Fiz. Khim. Stekla) 25(1): 61-6 (1999).

[gamma]-Radiation synthesis of nanocrystalline powders of copper(I) halides.
Yingjie, Z., Yitai, Q., Youfu, C., Mater. Sci. Eng., B B57(3): 247-50 (1999).

Radiation-induced defects in K₂SO₄: Cu crystals.
Nurakhmetov, T.N., Murzakhmetov, M.K., Akizhanov, R.N., Amandosov, A.T., Opt. Spectrosc. (Transl. of Opt. Spektrosk.) 86(4): 551-2 (1999).

Radiation dose effect on formation of 1,4-butanediol in [gamma]-radiolysis of the methanol - 2-propen-1-ol system at 20-200deg..
Silaev, M.M., Afanas'ev, A.M., Kalyazin, E.P., Vestn. Mosk. Univ., Ser. 2: Khim. 40(1): 53-5 (1999).

Experimental Studies on Related Topics

Electron drift and attachment in CHF₃ and its mixtures with argon.
Wang, Y.C., Christophorou, L.G., Olthoff, J.K., Verbrugge, J.K., Chem. Phys. Lett. 304(5-6): 303-8 (1999).

Temperature dependence of electron attachment to methylene chloride.
Pinnaduwage, L.A., Tav, C., McCorkle, D.L., Ding, W.X., J. Chem. Phys. 110(18): 9011-6 (1999).

Novel cascade of seven radical-mediated 6-endo-trig cyclisations leading to a unique all-trans, anti heptacycle.
Handa, S., Pattenden, G., J. Chem. Soc., Perkin Trans. 1 (8): 843-5 (1999).

A novel total synthesis of (+/-)-aspidospermidine.
Callaghan, O., Lampard, C., Kennedy, A.R., Murphy, J.A., J. Chem. Soc., Perkin Trans. 1 (8): 995-1001 (1999).

Novel tandem cyclizations reaction with electrophiles of [alpha]-aminoalkyl radicals.
Katritzky, A.R., Feng, D.M., Qi, M., Aurrecoechea, J.M., Suero, R., Aurrekoetxea, N., J. Org. Chem. 64(9): 3335-8 (1999).

Electrosynthesis of mono- and bisthianthrenium salts.
Houmam, A., Shukla, D., Kraatz, H.B., Wayner, D.D.M., J. Org. Chem. 64(9): 3342-5 (1999).

Subpicosecond optical sampling spectrometer using asynchronous tunable mode-locked lasers.
Takagi, Y., Adachi, S., Rev. Sci. Instrum. 70(5): 2218-24 (1999).

Multiphase Systems

XPS study of amorphous zirconium oxide films prepared by sol-gel.
Brenier, R., Mugnier, J., Mirica, E., Appl. Surf. Sci. 143(1-4): 85-91 (1999).

Theoretical studies of surface reactions on metals. I. Ethyl to ethylene conversion on Ni(1 0 0). II. Photodissociation of methane on platinum.
Whitten, J.L., Yang, H., Catal. Today 50(3-4): 603-12 (1999).

Studies on the photoassisted adsorption of gases on illuminated titania.
Bredemeyer, N., Hesse, D., Chem.-Ing.-Tech. 71(3): 238-41 (1999).

Intercalation of aliphatic carboxylates in hydrotalcite interlayers: Selective photochemical hydrogen abstraction by benzophenonecarboxylate.
Takagi, K., Saito, N., Shichi, T., Sawaki, Y., Chem. Lett. (4): 275-6 (1999).

Self-assembled monolayers derived from calix[4]resorcinarenes exhibiting excellent desorption-resistance and their applicability to surface energy photocontrol.
Oh, S.K., Nakagawa, M., Ichimura, K., Chem. Lett. (4): 349-50 (1999).

Study of mechanism of modified TiO₂ photocatalysts for photoreduction of CO₂ with surface photovoltage spectrum.
Xu, Y.-J., Xie, T.-F., Wang, D.-J., Wang, Y., Li, T.-J., Gaodeng Xuexiao Huaxue Xuebao 20(3): 461-3 (1999).

Ligand receptor dynamics at streptavidin-coated particle surfaces: A flow cytometric and spectrofluorimetric study.
Buranda, T., Jones, G.M., Nolan, J.P., Keij, J., Lopez, G.P., Sklar, L.A., J. Phys. Chem. B 103(17): 3399-410 (1999).

ESR study of radical generation in the course of catalytic pyrolysis of hydrocarbons.
Vasil'eva, N.A., Ermolaev, V.K., Kuz'mitskaya, S.Y., Kinet. Catal. 40(1): 100-4 (1999).

UV-induced reduction of molybdenum ions on the surface of alumina in the presence of carbon monoxide and nitrogen oxide.
Subbotina, I.R., Tarasov, A.L., Shelimov, B.N., Kazansky, V.B., Kinet. Catal. 40(1): 121-7 (1999).

Suppression of surface recombination on TiO₂ anatase photocatalysts in aqueous solutions containing alcohol.
Semenikhin, O.A., Kazarinov, V.E., Jiang, L., Hashimoto, K., Fujishima, A., Langmuir 15(11): 3731-7 (1999).

Computer simulation of energy transfer process.
Chen, B.-J., Qin, W.-P., Wazng, H.-Y., Xu, W., Huang, S.-H., Wuli Xuebao 48(3): 545-9 (1999).

Polymers

UV degradation patterns of nylon 6,6, nylon 6 and polyester fabrics used in PFD's (personal flotation devices).
Matthews, P.J., Book Pap. - Int. Conf. Exhib., AATCC : 537-45 (1998).

Photoinduced manipulations of photochromes in polymers: Anisotropy, modulation of the NLO properties and creation of surface gratings.
Atassi, Y., Chauvin, J., Delaire, J.A., Delouis, J.F., Fanton-Maltey, I., Nakatani, K., Pure Appl. Chem. 70(11): 2157-66 (1998).

Radiation induced main chain scission of polypropylene.
Dang, D.N., Tap Chi Hoa Hoc 36(3): 77-9 (1998).

TOF-SIMS analysis of chemical state changes in cresol-novolak photoresist surface caused by O₂ plasma downstream.
Saito, R., Ichinohe, Y., Kudo, M., Appl. Surf. Sci. 142(1-4): 460-4 (1999).

Radiation-induced polymerization of white phosphorus in multilayer emulsion.
Tarasova, N.P., Kochetov, I.N., Smetannikov, Y.V., Belyaev, S.G., Dokl. Akad. Nauk 364(6): 789-91 (1999).

Polymerization of an elaidic acid Langmuir film prepared on a terbium-containing subphase.
Derue, V., Alexandre, S., Valleton, J.M., J. Colloid Interface Sci. 213(2): 546-51 (1999).

Photo-probe study of siloxane polymers. I. Local free volume of an MQ-type silicone resin containig crosslinked nanoparticles probed by photoisomerization of azobenzene.
Yoshii, K., Yamashita, T., Machida, S., Horie, K., Itoh, M., Nishida, F., Morino, S., J. Non-Cryst. Solids 246(1-2): 90-103 (1999).

Low-loss passive optical waveguides based on photosensitive poly(pentafluorostyrene-co-glycidyl methacrylate).
Pitois, C., Vukmirovic, S., Hult, A., Wiesmann, D., Robertsson, M., Macromolecules 32(9): 2903-9 (1999).

Riboflavin triethanolamine as photoinitiator system of vinyl polymerization. A mechanistic study by laser flash photolysis.
Bertolotti, S.G., Previtali, C.M., Rufs, A.M., Encinas, M.V., Macromolecules 32(9): 2920-4 (1999).

Liquid-crystalline polymer networks: Effect of cross-linking on the stability of macroscopic molecular orientation.
Kurihara, S., Sakamoto, A., Nonaka, T., Macromolecules 32(9): 3150-3 (1999).

Is high-temperature light fading influenced by photochemical functions through polyester fiber parameters?
Herrmann, M., Hilfiker, R., Melliand Textilber. 80(4): 274-7 (1999).

Modification of PVC/ENR blend by electron beam irradiation: effect of crosslinking agents.
Ratnam, C.T., Zaman, K., Nucl. Instrum. Methods Phys. Res., Sect. B 152(2-3): 335-42 (1999).

Photopolymerization mechanisms of acrylates in poly(methyl methacrylate) films.
Urano, T., Ito, H., Takahama, K., Yamaoka, T., Polym. Adv. Technol. 10(4): 201-5 (1999).

Synthesis, characterization and polymerization characteristics of new dimethacrylates, derived from 3,3,5-trimethylcyclohexan-1-one-phenol adducts, as monomers for dental composites.
Culbertson, B.M., Xu, J.G., Tiba, A., Polym. Adv. Technol. 10(4): 206-14 (1999).

Photosensitization mechanisms in photopolymer coating film containing photoinitiators sensitized by aminochalcone-type dye for computer-to-photopolymer plate.
Urano, T., Nagao, T., Takada, A., Itoh, H., Polym. Adv. Technol. 10(4): 244-50 (1999).

Thermal decomposition and combustion of [gamma]-irradiated polyamide 6 containing phosphorus oxynitride or phospham.
Balabanovich, A., Levchik, S.V., Levchik, G.F., Schnabel, W., Wilkie, C.A., Polym. Degrad. Stab. 64(2): 191-5 (1999).

Influence of the exposure parameters on the mechanism of photooxidation of polypropylene.
Philippart, J.L., Sinturel, C., Arnaud, R., Gardette, J.L., Polym. Degrad. Stab. 64(2): 213-25 (1999).

Reactivity in radical polymerization of poly(2-oxazoline) macromonomers.
Shimano, Y., Sato, K., Kobayashi, S., Polym. J. (Tokyo) 31(3): 219-25 (1999).

Reactivity in the radical copolymerization of poly(2-oxazoline) macromonomers with methacrylate monomers.
Shimano, Y., Sato, K., Fukui, D., Onodera, Y., Kimura, Y., Polym. J. (Tokyo) 31(3): 296-302 (1999).

Radical propagation rate coefficient of N-inylcarbazole measured by pulsed-laser polymerization.
Ohoka, M., Misumi, S., Yamamoto, M., Polym. J. (Tokyo) 31(3): 316-7 (1999).

Time-resolved Forster energy transfer in polymer blends.
Dogariu, A., Gupta, R., Heeger, A.J., Wang, H., Synth. Met. 100(1): 95-100 (1999).

Enhanced photostability of poly(1,3-phenylene diphenylvinylene)-derivatives by diphenyl-substitution.
Koch, A.T.H., Harrison, N.T., Haylett, N., Daik, R., Feast, W.J., Friend, R.H., Synth. Met. 100(1): 113-22 (1999).

Biological and Medical Aspects

Photoinduced chlorophyll fluorescence oscillations of high plants leaves.
Nesterenko, T.V., Dunacv, K.G., Biofizika 43(2): 366-8 (1998).

Studies on phosphate effect of cytosine and its novel photoproduct.
Lin, F., Wang, W.-Q., Wu, J.-L., Chem. Res. Chin. Univ. 14(4): 365-9 (1998).

Change in the polyamine content, ornithine decarboxylase, and spermidine/spermine N¹-acetyltransferase activity of x-ray-irradiated human cultured cells.
Cho, S.-C., Yabutani, T., Fujita Gakuen Igakkaishi 22(1): 117-22 (1998).

Mimicking bacterial photosynthesis.
Gust, D., Moore, T.A., Moore, A.L., Pure Appl. Chem. 70(11): 2189-200 (1998).

Involvement of p53 in ionizing-radiation-induced DNA repair.
Mallya, S.M. Ph.D., Thesis, Univ. Connecticut, Storrs, CT, 1998, 89p.

The biosynthesis of barbamide - A radical pathway for "biohalogenation"?
Hartung, J., Angew. Chem., Int. Ed. Engl. 38(9): 1209-11 (1999).

Synthesis and photochemistry of a photolabile precursor of N-methyl-D-aspartate (NMDA) that is photolyzed in the microsecond time region and is suitable for chemical kinetic investigations of the NMDA receptor.
Gee, K.R., Niu, L., Schaper, K., Jayaraman, V., Hess, G.P., Biochemistry 38(10): 3140-7 (1999).

Synthesis and characterization of a photoactivatable glycoaryldiazirine for surface glycoengineering.
Chevolot, Y., Bucher, O., Leonard, D., Mathieu, H.J., Sigrist, H., Bioconjugate Chem. 10(2): 169-75 (1999).

Photo-induced DNA cleavage by water-soluble cationic fullerene derivatives.
Takenaka, S., Yamashita, K., Takagi, M., Hatta, T., Tsuge, O., Chem. Lett. (4): 321-2 (1999).

Photochemical reduction of NADP⁺ by zinc protoporphyrin reconstituted myoglobin as a simple model of photosystem I.
Nishiyama, K., Uchiyama, M., Mie, Y., Taniguchi, I., Chem. Lett. (4): 357-8 (1999).

Photo-induced reactions of sulfonated aluminum phthalocyanine with peptide.
Dong, R.A., Qiu, Y., Song, X.Q., Chin. Sci. Bull. 44(5): 431-3 (1999).

Interplay of orbital tuning and linker location in controlling electronic communication in porphyrin arrays.
Yang, S.I., Seth, J., Balasubramanian, T., Kim, D., Lindsey, J.S., Holten, D., Bocian, D.F., J. Am. Chem. Soc. 121(16): 4008-18 (1999).

Optimization of Arabidopsis thaliana DNA extraction for the analysis of 8-oxo-7,8-dihydro-2'-deoxyguanosine formation after gamma irradiation.
Dany, A.L., Triantaphylides, C., Cadet, J., Douki, T., J. Chim. Phys. Phys.-Chim. Biol. 96(1): 152-61 (1999).

Dihydrothienopsoralens: New furocoumarins as potential photoreacting agents.
Zoubir, B., Refouvelet, B., Aubin, F., Humbert, P., Xicluna, A., J. Heterocycl. Chem. 36(2): 509-13 (1999).

On the widespread occurrence of 3-methylidene-7,11,15-trimethylhexadecan-1,2-diol in the marine environment: a specific isoprenoid marker of chlorophyll photodegradation.
Cuny, P., Rontani, J.-F., Mar. Chem. 65(-4): 155-65 (1999).

Action of DNA repair endonuclease ERCC1/XPF in living cells.
Houtsmuller, A.B., Rademakers, S., Nigg, A.L., Hoogstraten, D., Hoeijmakers, J.H.J., Vermeulen, W., Science (Washington, D. C.) 284(5416): 958-61 (1999).

Solar Energy

Dye-sensitization of n-TiO₂ single-crystal electrodes with vapor-deposited oxometal phthalocyanines.
Taira, S., Miki, T., Yanagi, H., Appl. Surf. Sci. 143(1-4): 23-9 (1999).

Dye-sensitized TiO₂ solar cells: Structural and photoelectrochemical characterization of nanocrystalline electrodes formed from the hydrolysis of TiCl₄.
Park, N.G., Schlichthorl, G., van de Lagemaat, J., Cheong, H.M., Mascarenhas, A., Frank, A.J., J. Phys. Chem. B 103(17): 3308-14 (1999).

Industrial and Environmental Applications

Cleaner technologies of organic wastewater in Hong Kong dyeing and finishing factories.
Fung, P.C., Tsui, S.M. WEFTEC Asia Singapore 1998, Proc. Water Environ. Fed. Tech. Conf. Expo., Water Environment Federation, Alexandria, VA, 1998, Vol. 1, p.631-7

Quasipermanent photochemical gratings in a dual use photorefractive polymer composite.
Strutz, S.J., Hayden, L.M., Appl. Phys. Lett. 74(19): 2749-51 (1999).

Photocatalytic decomposition of acetaldehyde over TiO₂/SiO₂ catalyst.
Obuchi, E., Sakamoto, T., Nakano, K., Shiraishi, F., Chem. Eng. Sci. 54(10): 1525-30 (1999).

Photolytic and photocatalytic treatment of an aqueous solution containing microbial cells and organic compounds in an annular-flow reactor.
Shiraishi, F., Toyoda, K., Fukinbara, S., Obuchi, E., Nakano, K., Chem. Eng. Sci. 54(10): 1547-52 (1999).

Emission-poor photo-hardening of glass fiber-reinforced plastics.
Jung, T., Kohler, M., Coating 32(3): 90,2,4 (1999).

Physico-chemical properties of rice starch before and after gamma-ray irradiation.
Varavinit, S., Hanswasdi, C., Shobsngob, S., Foods Food Ingredients J. Jpn. 179: 67-71 (1999).

Study on catalyst for photodegradation of monocrotophos under sunlight.
Zhou, Y., Yue, L., Wu, M., Huanjing Wuran Yu Fangzhi 21(2): 17-8, 29 (1999).

Novel differential reactor for the measurement of overall quantum yields.
Davydov, L., Smirniotis, P.G., Pratsinis, S.E., Ind. Eng. Chem. Res. 38(4): 1376-83 (1999).

A deep desulfurization process for light oil by photosensitized oxidation using a triplet photosensitizer and hydrogen peroxide in an oil/water two-phase liquid-liquid extraction system.
Shiraishi, Y., Hara, H., Hirai, T., Komasawa, I., Ind. Eng. Chem. Res. 38(4): 1589-95 (1999).

Properties of polyisoprene-based pressure sensitive adhesives crosslinked by electron beam irradiation.
Yarusso, D.J., Rivard, R.J., Ma, J.J., J. Adhes. 69(3-4): 201-15 (1999).

Plasma polymer films as adhesion promoting primers for aluminum substrates. Part I: Characterization of films and film/substrate interfaces.
Taylor, C.E., Boerio, F.J., J. Adhes. 69(3-4): 217-36 (1999).

Photocatalytic activity of rutile Ti_1-xSn_xO₂ solid solutions.
Lin, J., Yu, J.C., Lo, D., Lam, S.K., J. Catal. 183(2): 368-72 (1999).

Photodegradation of the textile dye Reactive Black 5 in the presence of semiconducting oxides.
Poulios, I., Tsachpinis, I., J. Chem. Technol. Biotechnol. 74(4): 349-57 (1999).

Study of photodegradation of the pesticide ethiofencarb in aqueous and non-aqueous media, by gas chromatography-mass spectrometry.
Sanz-Asensio, J., Plaza-Medina, M., Martinez-Soria, M.T., Perez-Clavijo, M., J. Chromatogr., A 840(2): 235-47 (1999).

Light regime, riboflavin, and pH effects on 2,4-D photodegradation in water.
Harrison, S.K., Venkatesh, R., J. Environ. Sci. Health, Part B B34(3): 469-89 (1999).

Peroxidation treatment of dye manufacturing wastewater in the presence of ultraviolet light and ferrous ions.
Kang, S.-F., Liao, C.-H., Hung, H.-P., J. Hazard. Mater. 65(3): 317-33 (1999).

Ground and excited state electronic properties of halogenated tetraarylporphyrins. Tuning the building blocks for porphyrin-based photonic devices.
Yang, S.I., Seth, J., Strachan, J.-P., Gentemann, S., Kim, D., Holten, D., Lindsey, J.S., Bocian, D.F., J. Porphyrins Phthalocyanines 3(2): 117-47 (1999).

Metal filter, TiOMET, for environmental cleaning by photocatalyst.
Sasaki, F., Kogyo Zairyo 47(2): 113-6 (1999).

Surface hardening of a gray cast iron used for a diesel engine cylinder block using high-energy electron beam irradiation.
Choo, S.H., Lee, S., Kwon, S.J., Metall. Mater. Trans. A 30(5): 1211-21 (1999).

Photodegradation and photooxidation of thermoset and UV-cured acrylate polymers.
Decker, C., Zahouily, K., Polym. Degrad. Stab. 64(2): 293-304 (1999).

Role of humic acids in the TiO₂-photocatalyzed degradation of tetrachloroethene in water.
Selli, E., Baglio, D., Montanarella, L., Bidoglio, G., Water Res. 33(8): 1827-36 (1999).

Theoretical Studies

Analytical calculation of the intensity of EPR signals of radical pairs in reaction centers of photosynthesis in strong superhigh-frequency fields.
Kandrashkin, Y.E., Salikhov, K.M., Khim. Fiz. 17(11): 43-56 (1998).

Effect of fluctuations of classical medium on tunneling radiationless processes in molecules.
Belousov, A.V., Kovarskii, V.A., Zh. Eksp. Teor. Fiz. 114(6): 1944-53 (1998).

The B_1u and B_2u vibrational modes causing a D_6h to D_3h transition in benzene and in [18]- and [30]annulenes.
Yoshizawa, K., Tachibana, M., Yamabe, T., Bull. Chem. Soc. Jpn. 72(4): 697-700 (1999).

Crossover between the adiabatic and diabatic limits in photoinduced cooperative structural changes.
Koshino, K., Ogawa, T., J. Korean Phys. Soc. 34: S21-S4 (1999).

Effect of angle strain in conjugated cycloalkenylidenes. Singlet-triplet splitting of cyclobutenylidene and its ground-state intramolecular rearrangements.
Nicolaides, A., Matsushita, T., Tomioka, H., J. Org. Chem. 64(9): 3299-305 (1999).

Pulsed laser polymerization: Analytical solutions of the chain length distribution revisited.
Kornherr, A., Zifferer, G., Olaj, O.F., Macromol. Theory Simul. 8(3): 260-71 (1999).

Kinetic analysis of controlled/"living" radical polymerizations by simulations. 1. The importance of diffusion-controlled reactions.
Shipp, D.A., Matyjaszewski, K., Macromolecules 32(9): 2948-55 (1999).

Molecular dynamics study of non-equilibrium energy transport from a cylindrical track. Part II. Spike models for sputtering yield.
Bringa, E.M., Johnson, R.E., Dutkiewicz, L., Nucl. Instrum. Methods Phys. Res., Sect. B 152(2-3): 267-90 (1999).

Interaction of vacuum ultraviolet photons with molecules. Formation and dissociation dynamics of molecular superexcited states.
Hatano, Y., Phys. Rep. 313(3): 110-69 (1999).

Simulation of radiation-chemical behavior of americium in perchloric acid. I. 0.1-4 M HClO₄.
Vladimirova, M.V., Radiochemistry (Moscow) 41(1): 50-8 (1999).

Spectroscopic determination the water pair potential.
Fellers, R.S., Leforestier, C., Braly, L.B., Brown, M.G., Saykally, R.J., Science (Washington, D. C.) 284(5416): 945-8 (1999).

Energy exponents in thermal spike models of interface mixing.
Carter, G., Vacuum 53(3-4): 399-403 (1999).

Application of different quantum chemical Hamiltonians in developing quantitative structure-property relationship (QSPR) for photolysis of polycyclic aromatic hydrocarbons.
Chen, J.-w., Wang, S.-j., Zou, S.-w., Quan, X., Xue, D.-m., Zhao, Y.-z., Zhongguo Huanjing Kexue 19(2): 102-5 (1999).

Reviews

Biological free radicals.
Timmins, G.S., Davies, M.J., Electron Paramagn. Reson. 16: 1-49 (1998).

Radiation damage to DNA and related biomolecules.
Becker, D., Sevilla, M.D., Electron Paramagn. Reson. 16: 79-115 (1998).

Radical species in the catalytic pathways of enzymes from anaerobes.
Buckel, W., Golding, B.T., FEMS Microbiol. Rev. 22(5): 523-41 (1998).

Time, space and spectrally resolved photochemistry from ensembles to single molecules.
De Schryver, F.C., Pure Appl. Chem. 70(11): 2147-56 (1998).

Metal dihydride complexes: photochemical mechanisms for reductive elimination.
Perutz, R.N., Pure Appl. Chem. 70(11): 2211-20 (1998).

Electron paramagnetic resonance studies of radicals and ions with a low-coordinated phosphorus atom.
Geoffroy, M., Recent Res. Dev. Phys. Chem. 2(Pt. 1): 311-21 (1998).

Flash photolysis with time-resolved mass spectrometry.
Carr, R.W., Adv. Photochem. 25: 1-57 (1999).

Velocity mapping of multiphoton excited molecules.
Chandler, D.W., Parker, D.H., Adv. Photochem. 25: 59-106 (1999).

Catalysis of photoinduced electron transfer reactions.
Fukuzumi, S., Itoh, S., Adv. Photochem. 25: 107-72 (1999).

Photoinduced electron transfer reactions of organosilicon compounds.
Mizuno, K., Tamai, T., Sugimoto, A., Maeda, H., Adv. Electron Transfer Chem. 6: 131-65 (1999).

Laser trapping-spectroscopy-electrochemistry of individual microdroplets in solution.
Nakatani, K., Chikama, K., Kitamura, N., Adv. Photochem. 25: 173-223 (1999).

Photochemical solar cells based on dye-sensitization of nanocrystalline TiO₂.
Deb, S.K., Ellingson, R., Ferrere, S., Frank, A.J., Gregg, B.A., Nozik, A.J., Park, N., Schlichthorl, G., Zaban, A., AIP Conf. Proc. 462(NCPV Photovoltaics Program Review): 473-80 (1999).

How does radiation kill cells?
Cohen-Jonathan, E., Bernhard, E.J., McKenna, W.G., Curr. Opin. Chem. Biol. 3(1): 77-83 (1999).

Design and development of a titanium oxide photocatalyst able to work effectively under visible light irradiation by an advanced metal ion-implantation method.
Anpo, M., Takeuchi, M., Kishiguchi, S., Yamashita, H., Hyomen Kagaku 20(2): 60-5 (1999).

Photocatalysis by silica.
Tanaka, T., Yoshida, H., Hyomen Kagaku 20(2): 73-8 (1999).

Photo-induced super-hydrophilicity of TiO₂ surface.
Hashimoto, K., Watanabe, T., Hyomen Kagaku 20(2): 85-93 (1999).

Advances in oxidation of aromatic hydrocarbons to aromatic acids.
Yin, X., Chen, Z., Jiang, Q., Zong, Z., Meitan Zhuanhua 22(1): 19-22 (1999).

Photo-activatable caged peptides and proteins.
Tatsu, Y., Shigeri, Y., Yumoto, N., Seikagaku 71(3): 197-201 (1999).

Chemistry of the tropospheric aerosol and of clouds.
Georgii, H.W., Warneck, P., Top. Phys. Chem. 6(Global Aspects of Atmospheric Chemistry): 111-79 (1999).

Tables of rate coefficients.
Top. Phys. Chem. 6(Global Aspects of Atmospheric Chemistry): 323-9 (1999).

The Role of Rydberg States in Spectroscopy and Photochemistry: Low and High Rydberg States. [In: Understanding Chem. React., 1999; 20]. Sandorfy, C., Editor., Kluwer, Dordrecht, The Netherlands, 1999, 512p.

Solvation of radicals in small clusters.
Fernandez, J.A., Yao, J., Bray, J.A., Bernstein, E.R., Struct. Dyn. Electron. Excited States, J. Laane, H. Takahashi and A. Bandrauk (eds.), Springer, Berlin, Germany, 1999, p.71-109

Excited state dynamics and chemical control of large molecules.
Vachev, V.D., Frederick, J.H., Struct. Dyn. Electron. Excited States, J. Laane, H. Takahashi and A. Bandrauk (eds.), Springer, Berlin, Germany, 1999, p.137-62